Igneous Crystallization Simulator: Bowen's Reaction Series in Action

simulator intermediate ~10 min
Loading simulation...
Andesite / Diorite — intermediate composition, 42% crystallized

At 1100°C with 55% SiO₂, the magma is approximately 42% crystallized with plagioclase and pyroxene as the dominant mineral phases, producing an intermediate igneous rock.

Formula

φ = 1 - exp(-k × (T_liquidus - T) / ΔT)
d = d₀ × (rate_ref / coolingRate)^0.5
η = η₀ × exp(E_a / RT) × (1 + 2.5φ)

From Melt to Mineral

Deep beneath volcanoes and mid-ocean ridges, silicate magma begins its transformation into solid rock. As temperature drops, the first crystals nucleate — tiny seeds of olivine or Ca-rich plagioclase that grow outward into the surrounding melt. The sequence of mineral appearance follows Bowen's reaction series, one of the foundational frameworks of igneous petrology established through decades of laboratory crystallization experiments.

Bowen's Reaction Series

The discontinuous branch (olivine → pyroxene → amphibole → biotite) and continuous branch (Ca-plagioclase → Na-plagioclase) describe how mineral chemistry evolves as magma cools. Early-formed crystals may react with the remaining melt to form new minerals, or they may be physically separated by crystal settling — a process called fractional crystallization that can produce a range of rock compositions from a single parent magma.

Texture Tells the Story

Grain size is a direct record of cooling history. Plutonic rocks like granite cool over millions of years deep underground, growing crystals visible to the naked eye. Volcanic rocks like basalt erupt and solidify in hours to days, producing microscopic crystals or even glass. Porphyritic textures — large crystals in a fine matrix — reveal a two-stage cooling history, beginning slowly at depth and ending rapidly at the surface.

Composition and Viscosity

Silica content controls both the mineral assemblage and the physical behavior of magma. Low-silica (mafic) magmas are hot and fluid, producing effusive lava flows and rocks rich in dark minerals. High-silica (felsic) magmas are cooler and extremely viscous, often erupting explosively. This viscosity-composition relationship explains why shield volcanoes (basaltic) and stratovolcanoes (andesitic–rhyolitic) have such different eruption styles and hazard profiles.

FAQ

What is Bowen's reaction series?

Bowen's reaction series describes the order in which minerals crystallize from cooling magma. Olivine and Ca-plagioclase crystallize first at high temperatures, followed by pyroxene, amphibole, biotite, and finally quartz and K-feldspar at lower temperatures. It was established by N.L. Bowen through laboratory experiments in the early 20th century.

How does cooling rate affect igneous rock texture?

Slow cooling (intrusive/plutonic) produces coarse-grained rocks like granite because crystals have time to grow large. Rapid cooling (extrusive/volcanic) produces fine-grained rocks like basalt. Extremely rapid cooling can create volcanic glass (obsidian) with no visible crystals.

What determines whether a rock is mafic or felsic?

Silica content is the primary classifier: mafic rocks have less than 52% SiO₂ and are rich in iron and magnesium minerals (olivine, pyroxene), while felsic rocks exceed 63% SiO₂ and are dominated by quartz and feldspar. Intermediate rocks fall between these ranges.

Why does water content matter in magma crystallization?

Dissolved water lowers the solidus temperature, reduces melt viscosity, and stabilizes hydrous minerals like amphibole and biotite. Water-rich magmas can remain liquid at lower temperatures and produce mineral assemblages distinct from dry melts of the same composition.

Sources

Embed

<iframe src="https://homo-deus.com/lab/petrology/igneous-crystallization/embed" width="100%" height="400" frameborder="0"></iframe>
View source on GitHub