engineering

Distillation & Separation Processes

Simulate distillation and vapor-liquid equilibrium — McCabe-Thiele binary distillation stages, isothermal flash drum calculations, T-xy VLE diagrams, Raoult's law for ideal solutions, and azeotropic distillation with entrainer selection using real-time interactive visualizations.

distillationseparation processesMcCabe-Thieleflash drumvapor-liquid equilibriumRaoult's lawazeotropechemical engineering

Distillation is the most widely used separation technique in the chemical process industries, responsible for purifying everything from petroleum fractions and pharmaceutical intermediates to drinking water and beverage spirits. The process exploits differences in component volatilities: when a liquid mixture is partially vaporized, the vapor phase enriches in the more volatile component while the liquid retains the heavier species. Understanding vapor-liquid equilibrium is the key to designing efficient columns.

These simulations let you step through McCabe-Thiele graphical constructions for binary distillation, solve isothermal flash drum mass balances, plot T-xy phase diagrams from Antoine correlations, explore Raoult's law for ideal solutions, and investigate azeotropic systems that defeat simple distillation — all with physically accurate thermodynamic models and animated canvas visualizations that update as you adjust parameters.

5 interactive simulations

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Azeotropic Distillation & Entrainer

Investigate azeotropic behavior in binary systems — visualize how positive deviations from Raoult's law create minimum-boiling azeotropes that limit ordinary distillation, and explore entrainer-based separation strategies

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Isothermal Flash Drum Calculation

Solve the isothermal flash problem for a binary mixture — determine vapor fraction, liquid and vapor compositions using the Rachford-Rice equation with animated phase envelope visualization

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McCabe-Thiele Binary Distillation

Construct a McCabe-Thiele diagram for binary distillation — step off theoretical stages between operating lines and the equilibrium curve to determine the number of ideal plates required for a given separation

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Raoult's Law & Ideal Solutions

Explore Raoult's law for ideal binary mixtures — visualize partial pressures, total pressure, and deviation from ideality as you adjust pure-component vapor pressures and composition

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Vapor-Liquid Equilibrium T-xy Diagram

Generate T-xy phase diagrams for binary mixtures using Antoine equation vapor pressures — visualize bubble-point and dew-point curves, tie lines, and the two-phase region